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Flexible electrodes for the future of light detection

19 novembre 2025 à 09:04

Photodetectors convert light into electrical signals and are essential in technologies ranging from consumer electronics and communications to healthcare. They also play a vital role in scientific research. Researchers are continually working to improve their sensitivity, response speed, spectral range, and design efficiency.

Since the discovery of graphene’s remarkable electrical properties, there has been growing interest in using graphene and other two-dimensional (2D) materials to advance photodetection technologies. When light interacts with these materials, it excites electrons that must travel to a nearby contact electrode to generate an electrical signal. The ease with which this occurs depends on the work functions of the materials involved, specifically, the difference between them, known as the Schottky barrier height. Selecting an optimal combination of 2D material and electrode can minimize this barrier, enhancing the photodetector’s sensitivity and speed. Unfortunately, traditional electrode materials have fixed work functions which are limiting 2D photodetector technology.

PEDOT:PSS is a widely used electrode material in photodetectors due to its low cost, flexibility, and transparency. In this study, the researchers have developed PEDOT:PSS electrodes with tunable work functions ranging from 5.1 to 3.2 eV, making them compatible with a variety of 2D materials and ideal for optimizing device performance in metal-semiconductor-metal architectures. In addition, their thorough investigation demonstrates that the produced photodetectors performed excellently, with a significant forward current flow (rectification ratio ~10⁵), a strong conversion of light to electrical output (responsivity up to 1.8 A/W), and an exceptionally high Ilight/Idark ratio of 10⁸. Furthermore, the detectors were highly sensitive with low noise, had very fast response times (as fast as 3.2 μs), and thanks to the transparency of PEDOT:PSS, showed extended sensitivity into the near-infrared region.

This study demonstrates a tunable, transparent polymer electrode that enhances the performance and versatility of 2D photodetectors, offering a promising path toward flexible, self-powered, and wearable optoelectronic systems, and paving the way for next-generation intelligent interactive technologies.

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A homogenous polymer design with widely tunable work functions for high-performance two-dimensional photodetectors

Youchen Chen et al 2025 Rep. Prog. Phys. 88 068003

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Two-dimensional material/group-III nitride hetero-structures and devices by Tingting LinYi ZengXinyu LiaoJing LiChangjian Zhou and Wenliang Wang (2025)

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Teaching machines to understand complexity

12 novembre 2025 à 09:05

Complex systems model real-world behaviour that is dynamic and often unpredictable. They are challenging to simulate because of nonlinearity, where small changes in conditions can lead to disproportionately large effects; many interacting variables, which make computational modelling cumbersome; and randomness, where outcomes are probabilistic. Machine learning is a powerful tool for understanding complex systems. It can be used to find hidden relationships in high-dimensional data and predict the future state of a system based on previous data.

This research develops a novel machine learning approach for complex systems that allows the user to extract a few collective descriptors of the system, referred to as inherent structural variables. The researchers used an autoencoder (a type of machine learning tool) to examine snapshots of how atoms are arranged in a system at any moment (called instantaneous atomic configurations). Each snapshot is then matched to a more stable version of that structure (an inherent structure), which represents the system’s underlying shape or pattern after thermal noise is removed. These inherent structural variables enable the analysis of structural transitions both in and out of equilibrium and the computation of high-resolution free-energy landscapes. These are detailed maps that show how a system’s energy changes as its structure or configuration changes, helping researchers understand stability, transitions, and dynamics in complex systems.

The model is versatile, and the authors demonstrate how it can be applied to metal nanoclusters and protein structures. In the case of Au147 nanoclusters (well-organised structures made up of 147 gold atoms), the inherent structural variables reveal three main types of stable structures that the gold nanocluster can adopt: fcc (face-centred cubic), Dh (decahedral), and Ih (icosahedral). These structures represent different stable states that a nanocluster can switch between, and on the high-resolution free-energy landscape, they appear as valleys. Moving from one valley to another isn’t easy, there are narrow paths or barriers between them, known as kinetic bottlenecks.

The researchers validated their machine learning model using Markov state models, which are mathematical tools that help analyse how a system moves between different states over time, and electron microscopy, which images atomic structures and can confirm that the predicted structures exist in the gold nanoclusters. The approach also captures non-equilibrium melting and freezing processes, offering insights into polymorph selection and metastable states. Scalability is demonstrated up to Au309 clusters.

The generality of the method is further demonstrated by applying it to the bradykinin peptide, a completely different type of system, identifying distinct structural motifs and transitions. Applying the method to a biological molecule provides further evidence that the machine learning approach is a flexible, powerful technique for studying many kinds of complex systems. This work contributes to machine learning strategies, as well as experimental and theoretical studies of complex systems, with potential applications across liquids, glasses, colloids, and biomolecules.

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Inherent structural descriptors via machine learning

Emanuele Telari et al 2025 Rep. Prog. Phys. 88 068002

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Complex systems in the spotlight: next steps after the 2021 Nobel Prize in Physics by Ginestra Bianconi et al (2023)

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Making quantum computers more reliable

5 novembre 2025 à 09:42

Quantum error correction codes protect quantum information from decoherence and quantum noise, and are therefore crucial to the development of quantum computing and the creation of more reliable and complex quantum algorithms. One example is the five-qubit error correction code, five being the minimum number of qubits required to fix single-qubit errors. These contain five physical qubits (a basic off/on unit of quantum information made using trapped ions, superconducting circuits, or quantum dots) to correct one logical qubit (a collection of physical qubits arranged in such a way as to correct errors). Yet imperfections in the hardware can still lead to quantum errors.

A method of testing quantum error correction codes is self-testing. Self-testing is a powerful tool for verifying quantum properties using only input-output statistics, treating quantum devices as black boxes. It has evolved from bipartite systems consisting of two quantum subsystems, to multipartite entanglement, where entanglement is among three or more subsystems, and now to genuinely entangled subspaces, where every state is fully entangled across all subsystems. Genuinely entangled subspaces offer stronger, guaranteed entanglement than general multipartite states, making them more reliable for quantum computing and error correction.

In this research, self-testing techniques are used to certify genuinely entangled logical subspaces within the five-qubit code on photonic and superconducting platforms. This is achieved by preparing informationally complete logical states that span the entire logical space, meaning the set is rich enough to fully characterize the behaviour of the system. They deliberately introduce basic quantum errors by simulating Pauli errors on the physical qubit, which mimics real-world noise. Finally, they use mathematical tests known as Bell inequalities, adapted to the framework used in quantum error correction, to check whether the system evolves in the initial logical subspaces after the errors are introduced.

Extractability measures tell you how close the tested quantum system is to the ideal target state, with 1 being a perfect match. The certification is supported by extractability measures of at least 0.828 ± 0.006 and 0.621 ± 0.007 for the photonic and superconducting systems, respectively. The photonic platform achieved a high extractability score, meaning the logical subspace was very close to the ideal one. The superconducting platform had a lower score but still showed meaningful entanglement. These scores show that the self-testing method works in practice and confirm strong entanglement in the five-qubit code on both platforms.

This research contributes to the advancement of quantum technologies by providing robust methods for verifying and characterizing complex quantum structures, which is essential for the development of reliable and scalable quantum systems. It also demonstrates that device-independent certification can extend beyond quantum states and measurements to more general quantum structures.

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Certification of genuinely entangled subspaces of the five qubit code via robust self-testing

Yu Guo et al 2025 Rep. Prog. Phys. 88 050501

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Quantum error correction for beginners by Simon J DevittWilliam J Munro and Kae Nemoto (2013)

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Quantum ferromagnets without the usual tricks: a new look at magnetic excitations

5 novembre 2025 à 09:36

For almost a century, physicists have tried to understand why and how materials become magnetic. From refrigerator magnets to magnetic memories, the microscopic origins of magnetism remain a surprisingly subtle puzzle — especially in materials where electrons behave both like individual particles and like a collective sea.

In most transition-metal compounds, magnetism comes from the dance between localized and mobile electrons. Some electrons stay near their home atoms and form tiny magnetic moments (spins), while others roam freely through the crystal. The interaction between these two types of electrons produces “double-exchange” ferromagnetism — the mechanism that gives rise to the rich magnetic behaviour of materials such as manganites, famous for their colossal magnetoresistance (a dramatic change in electrical resistance under a magnetic field). Traditionally, scientists modelled this behaviour by treating the localized spins as classical arrows — big and well-defined, like compass needles. This approximation works well enough for explaining basic ferromagnetism, but experiments over the last few decades have revealed strange features that defy the classical picture. In particular, neutron scattering studies of manganites showed that the collective spin excitations, called magnons, do not behave as expected. Their energy spectrum “softens” (the waves slow down) and their sharp signals blur into fuzzy continua — a sign that the magnons are losing their coherence. Until now, these effects were usually blamed on vibrations of the atomic lattice (phonons) or on complex interactions between charge, spin, and orbital motion.

2025-november-researchgroup-Herbrych
Left to right: Adriana Moreo and Elbio Dagotto from University of Tennessee (USA), Takami Tohyama from Tokyo University of Science (Japan), and Marcin Mierzejewski and Jacek Herbrych from Wrocław University of Technology (Courtesy: Herbrych/Wrocław University of Science and Technology)

A new theoretical study challenges that assumption. By going fully quantum mechanical — treating every localized spin not as a classical arrow but as a true quantum object that can fluctuate, entangle, and superpose — the researchers have reproduced these puzzling experimental observations without invoking phonons at all. Using two powerful model systems (a quantum version of the Kondo lattice and a two-orbital Hubbard model), the team simulated how electrons and spins interact when no semiclassical approximations are allowed. The results reveal a subtle quantum landscape. Instead of a single type of electron excitation, the system hosts two. One behaves like a spinless fermion — a charge carrier stripped of its magnetic identity. The other forms a broad, “incoherent” band of excitations arising from local quantum triplets. These incoherent states sit close to the Fermi level and act as a noisy background — a Stoner-like continuum — that the magnons can scatter off. The result: magnons lose their coherence and energy in just the way experiments observe.

Perhaps most surprisingly, this mechanism doesn’t rely on the crystal lattice at all. It’s an intrinsic consequence of the quantum nature of the spins themselves. Larger localized spins, such as those in classical manganites, tend to suppress the effect — explaining why decoherence is weaker in some materials than others. Consequently, the implications reach beyond manganites. Similar quantum interplay may occur in iron-based superconductors, ruthenates, and heavy-fermion systems where magnetism and superconductivity coexist. Even in materials without permanent local moments, strong electronic correlations can generate the same kind of quantum magnetism.

In short, this work uncovers a purely electronic route to complex magnetic dynamics — showing that the quantum personality of the electron alone can mimic effects once thought to require lattice distortions. By uniting electronic structure and spin excitations under a single, fully quantum description, it moves us one step closer to understanding how magnetism truly works in the most intricate materials.

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Magnon damping and mode softening in quantum double-exchange ferromagnets

A Moreo et al 2025 Rep. Prog. Phys. 88 068001

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Nanoscale electrodynamics of strongly correlated quantum materials by Mengkun LiuAaron J Sternbach and D N Basov (2017)

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Interface engineered ferromagnetism

29 octobre 2025 à 09:40

Exchange-coupled interfaces offer a powerful route to stabilising and enhancing ferromagnetic properties in two-dimensional materials, such as transition metal chalcogenides. These materials exhibit strong correlations among charge, spin, orbital, and lattice degrees of freedom, making them an exciting area for emergent quantum phenomena.

Cr₂Te₃’s crystal structure naturally forms layers that behave like two-dimensional sheets of magnetic material. Each layer has magnetic ordering (ferromagnetism), but the layers are not tightly bonded in the third dimension and are considered “quasi-2D.” These layers are useful for interface engineering. Using a vacuum-based technique for atomically precise thin-film growth, known as molecular beam epitaxy, the researchers demonstrate wafer-scale synthesis of Cr₂Te₃ down to monolayer thickness on insulating substrates. Remarkably, robust ferromagnetism persists even at the monolayer limit, a critical milestone for 2D magnetism.

When Cr₂Te₃ is proximitized (an effect that occurs when one material is placed in close physical contact with another so that its properties are influenced by the neighbouring material) to a topological insulator, specifically (Bi,Sb)₂Te₃, the Curie temperature, the threshold between ferromagnetic and paramagnetic phases, increases from ~100 K to ~120 K. This enhancement is experimentally confirmed via polarized neutron reflectometry, which reveals a substantial boost in magnetization at the interface.

Theoretical modelling attributes this magnetic enhancement to the Bloembergen–Rowland interaction which is a long-range exchange mechanism mediated by virtual intraband transitions. Crucially, this interaction is facilitated by the topological insulator’s topologically protected surface states, which are spin-polarized and robust against disorder. These states enable long-distance magnetic coupling across the interface, suggesting a universal mechanism for Curie temperature enhancement in topological insulator-coupled magnetic heterostructures.

This work not only demonstrates a method for stabilizing 2D ferromagnetism but also opens the door to topological electronics, where magnetism and topology are co-engineered at the interface. Such systems could enable novel quantum hybrid devices, including spintronic components, topological transistors, and platforms for realizing exotic quasiparticles like Majorana fermions.

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Enhanced ferromagnetism in monolayer Cr2Te3 via topological insulator coupling

Yunbo Ou et al 2025 Rep. Prog. Phys. 88 060501

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Interacting topological insulators: a review by Stephan Rachel (2018)

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