Transparent and insulating aerogel could boost energy efficiency of windows
An aerogel material that is more than 99% transparent to light and is an excellent thermal insulator has been developed by Ivan Smalyukh and colleagues at the University of Colorado Boulder in the US. Called MOCHI, the material can be manufactured in large slabs and could herald a major advance in energy-efficient windows.
While the insulating properties of building materials have steadily improved over the past decades, windows have consistently lagged behind. The problem is that current materials used in windows – mostly glass – have an inherent trade-off between insulating ability and optical transparency. This is addressed to some extent by using two or three layers of glass in double- and triple-glazed windows. However, windows remain the largest source of heat loss from most buildings.
A solution to the window problem could lie with aerogels in which the liquid component of a regular gel is replaced with air. This creates solid materials with networks of pores that make aerogels the lightest solid materials ever produced. If the solid component is a poor conductor of heat, then the aerogel will be an extremely good thermal insulator.
“Conventional aerogels, like the silica and cellulose based ones, are common candidates for transparent, thermally insulating materials,” Smalyukh explains. “However, their visible-range optical transparency is intrinsically limited by the scattering induced by their polydisperse pores – which can range from nanometres to micrometres in scale.”
Hazy appearance
While this problem can be overcome fairly easily in thin aerogel films, creating appropriately-sized pores on the scale of practical windows has so far proven much more difficult, leading to a hazy, translucent appearance.
Now, Smalyukh’s team has developed a new fabrication technique involving a removable template. Their approach hinges on the tendency of surfactant molecules called CPCL to self-assemble in water. Under carefully controlled conditions, the molecules spontaneously form networks of cylindrical tubes, called micelles. Once assembled, the aerogel precursor – a silicone material called polysiloxane – condenses around the micelles, freezing their structure in place.
“The ensuing networks of micelle-templated polysiloxane tubes could be then preserved upon the removal of surfactant, and replacing the fluid solvent with air,” Smalyukh describes. The end result was a consistent mesoporous structure, with pores ranging from 2–50 nm in diameter. This is too small to scatter visible light, but large enough to interfere with heat transport.
As a result, the mesoporous, optically clear heat insulator (MOCHI) maintains its transparency even when fabricated in slabs over 3 cm thick and a square metre in area. This suggests that it could be used to create practical windows.
High thermal performance
“We demonstrated thermal conductivity lower than that of still air, as well as an average light transmission above 99%,” Smalyukh says. “Therefore, MOCHI glass units can provide a similar rate of heat transfer to high-performing building roofs and walls, with thicknesses comparable to double pane windows.”
If rolled out on commercial scales, this could lead to entirely new ways to manage interior heating and cooling. According to the team’s calculations, a building retrofitted with MOCHI windows could boost its energy efficiency from around 6% (a typical value in current buildings) to over 30%, while reducing the heat energy passing through by around 50%.
With its ability to admit light while blocking heat transport, the researchers suggest that MOCHI could unlock entirely new functionalities for conventional windows. “Such transparent insulation also allows for efficient harnessing of thermal energy from unconcentrated solar radiation in different climate zones, promising the use of parts of opaque building envelopes as solar thermal energy generating panels,” Smalyukh adds.
The new material is described in Science.
The post Transparent and insulating aerogel could boost energy efficiency of windows appeared first on Physics World.














